Calcium nitrate

chemical compound

Calcium nitrate, also known as Norwegian saltpeter, is a chemical compound. Its chemical formula is Ca(NO3)2. It contains calcium and nitrate ions.

Calcium nitrate
Names
Other names
Kalksalpeter, nitrocalcite, Norwegian saltpeter, lime nitrate
Identifiers
  • 10124-37-5 checkY
  • 13477-34-4 (tetrahydrate) ☒N
3D model (JSmol)
ChemSpider
ECHA InfoCard100.030.289
PubChem CID
RTECS number
  • EW2985000
UNII
UN number1454
CompTox Dashboard (EPA)
SMILES
  • [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Ca(NO3)2
Molar mass164.088 g/mol (anhydrous)
236.15 g/mol (tetrahydrate)
Appearancecolorless solid
hygroscopic
Density2.504 g/cm3 (anhydrous)
1.896 g/cm3 (tetrahydrate)
Melting point 561 °C (1,042 °F; 834 K) (anhydrous)
42.7 °C (109 °F; 316 K) (tetrahydrate)
Boiling pointdecomposes (anhydrous)
132 °C (270 °F; 405 K) (tetrahydrate)
anhydrous:
1212 g/L (20 °C)
2710 g/L (40 °C)
tetrahydrate:
1050 g/L (0 °C)
1290 g/L (20 °C)
3630 g/L (100 °C)
Solubilitysoluble in ammonia
almost insoluble in nitric acid
Solubility in ethanol51.4 g/100 g (20 °C)
62.9 g/100 g (40 °C)[1]
Solubility in methanol134 g/100 g (10 °C)
144 g/100 g (40 °C)
158 g/100 g (60 °C)[1]
Solubility in acetone16.8 g/kg (20 °C)[1]
Acidity (pKa)6.0
-45.9·10−6 cm3/mol
Structure
cubic (anhydrous)
monoclinic (tetrahydrate)
Hazards
NFPA 704

0
2
1
 
R-phrasesR22, R41
Flash pointNon-flammable
Related compounds
Other anionsCalcium sulfate
Calcium chloride
Other cationsMagnesium nitrate
Strontium nitrate
Barium nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Properties

Calcium nitrate is a colorless solid. It is an oxidizing agent. It absorbs water from the air. It decomposes to make nitrogen dioxide and calcium oxide when heated.

Preparation

Calcium nitrate is made by reacting calcium hydroxide or calcium carbonate with nitric acid. It is made when nitric acid reacts with calcium phosphate. It can be made by reacting ammonium nitrate and calcium hydroxide.

Uses

Calcium nitrate is used in fertilizers to add nitrogen to the soil. It can be complexed with urea to make a different nitrogen fertilizer.

References