Vanadium(III) acetylacetonate

Vanadium(III) acetylacetonate
Names
	Other names Vanadium tris(2,4-pentanedionate); Tris(2,4-pentanedionato) vanadium; Vanadium acetylacetonate; Vanadium tris(acetylacetonate);
Identifiers
CAS Number	13476-99-8 ;
3D model (JSmol)	Interactive image;
ChemSpider	22199456;
ECHA InfoCard	100.033.403
EC Number	236-759-1;
PubChem CID	5377225;
	InChI InChI=1S/3C5H8O2.V/c31-4(6)3-5(2)7;/h33,6H,1-2H3;/b3*4-3-; Key: MFWFDRBPQDXFRC-LNTINUHCSA-N;
	SMILES CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[V];
Properties
Chemical formula	C15H21O6V
Molar mass	348.269 g·mol−1
Appearance	Brown solid
Density	1.334 g/cm3
Melting point	184 °C (363 °F; 457 K)
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H301, H311, H315, H318, H319, H330, H335
Precautionary statements	P260, P261, P264, P270, P271, P280, P284, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Vanadium(III) acetylacetonate is the coordination compound with the formula V(C₅H₇O₂)₃, sometimes designated as V(acac)₃. It is an orange-brown solid that is soluble in organic solvents.

Structure and synthesis

The complex has idealized D₃ symmetry.^[1] Like other V(III) compounds, it has a triplet ground state.

The compound is prepared by reduction of ammonium vanadate in the presence of acetylacetone.^[2]

Applications and research

V(acac)₃ is a common precatalyst for the production of EPDM polymers.^[3]

It has also been shown to be a precursor to vanadium pentoxide nanostructures.^[4]

References

[1]

[2]

[3]

[4]

Names

Other names Vanadium tris(2,4-pentanedionate) Tris(2,4-pentanedionato) vanadium Vanadium acetylacetonate Vanadium tris(acetylacetonate)
Identifiers
CAS Number	13476-99-8^Y
3D model (JSmol)	Interactive image
ChemSpider	22199456
ECHA InfoCard	100.033.403
EC Number	236-759-1
PubChem CID	5377225
InChI InChI=1S/3C5H8O2.V/c31-4(6)3-5(2)7;/h33,6H,1-2H3;/b3*4-3-; Key: MFWFDRBPQDXFRC-LNTINUHCSA-N
SMILES CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[V]
Properties
Chemical formula	C₁₅H₂₁O₆V
Molar mass	348.269 g·mol⁻¹
Appearance	Brown solid
Density	1.334 g/cm³
Melting point	184 °C (363 °F; 457 K)
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H301, H311, H315, H318, H319, H330, H335
Precautionary statements	P260, P261, P264, P270, P271, P280, P284, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references