Neodymium-doped yttrium lithium fluoride (Nd:YLF) is a lasing medium for arc lamp-pumped and diode-pumped solid-state lasers. The YLF crystal (LiYF4) is naturally birefringent, and commonly used laser transitions occur at 1047 nm and 1053 nm.[1]
It is used in Q-switched systems in part due to its relatively long fluorescence lifetime.As with Nd:YAG lasers, harmonic generation is frequently employed with Q-switched Nd:YLF to produce shorter wavelengths. A common applicationof frequency-doubled Nd:YLF pulses is to pump ultrafast Ti:Sapphire chirped-pulse amplifiers.
Neodymium-doped YLF can provide higher pulse energies than Nd:YAG for repetition rates of a few kHz or less. Compared to Nd:YAG, the Nd:YLF crystal is very brittle and fractures easily. It is also slightly water-soluble — a YLF laser rod may very slowly dissolve in cooling water which surrounds it.[1]
Physical and chemical properties
Materials: Nd:LiYF4
Modulus of Elasticity: 85 GPa
Crystal Structure: Tetragonal
Cell Parameters: a=5.16 Å , c=10.85 Å
Melting Point: 819 °C
Mohs Hardness: 4~5[2]
Density: 3.99 g/cm^3
Thermal Conductivity: 0.063 W/cm/K
Specific Heat: 0.79 J/g/K