Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.
Hydrotalcite can contain carbonate and nitrate ions between its layers. Magnesium can be substituted by nickel, cobalt or copper.[1]
Oxycarbonitrates containing an alkaline earth metal and cuprate and nitrate and carbonate anions in layers, form a family of superconducting materials.[2]
List
| name | formula | ratio | formula weight | crystal system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|---|---|---|
| Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate | (Co(NH3)5(CO3))(NO3)·H2O | 1:1 | monoclinic | P21/c | a = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4 | 931.2 | [3] | |||
| (Co(NH3)4CO3)(NO3)·(H2O)0.5 | 1:1 | monoclinic | P21/n | a=7.4319 b=22.647 c=10.4103 β=92.052° Z=8 | 1756 | 1.95 | violet-red; loses water at 125°C | [4][5] | ||
| (Co(NH3)4(CO3)(NO3))2·H2O | 1:1 | monoclinic | P21/n | a=7.4960 b=22.673 c=10.513 β=91.41° Z=4 | 1786.12 | 1.915 | [6] | |||
| [Co(NH3)5CO3]NO3·1/2H2O | 1:1 | monoclinic | P21/m | a=7.6661 b=9.6212 c=7.0725 β=106.261° Z=2 | 500.78 | 1.82 | pink | [7] | ||
| [Co(NH3)5CO3]NO3·H2O | 1:1 | monoclinic | P21 | a = 7.6733 b = 9.6398 c = 7.0852 β = 106.195° | 1.87 | pink | [8] | |||
| Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate | (Co(CO3)(NH3)4)(NO3) | 1:1 | monoclinic | P21/c | a = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4 | 931.2 | pink | [9] | ||
| [(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O | 1:2 | triclinic | P1 | a=7.7038 b=9.672 c=10.861 α=104.826° β=109.405° γ=91.553° | [10] | |||||
| cis-(Carbonato-O,O')-bis(2,2'-bipyridine)-cobalt(iii) nitrate pentahydrate | [Co(C10H8N2)2(CO3)]NO3·5H2O | monoclinic | C2/c | a=10.931 b=16.039 c=14.435β=101.94° Z=4 | 2476 | [11] | ||||
| Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 | 3:2 | 1029.39 | hexagonal | P63/mcm | a = 9.5732 c = 15.820 Z=2 | 1255.6 | 2.723 | UV cut off 231 nm; (-) uniaxial; birefringence 0.14 @ 546 nm | [12] | |
| Na3Rb6(CO3)3(NO3)2Br·6H2O | 3:2 | hexagonal | P63/mcm | a=9.6086 c=15.864 Z=2 | [13] | |||||
| N0.2C0.8Sr3Cu2O7.0 | [2] | |||||||||
| C0.8N0.2Sr2CuO5.3 | [14] | |||||||||
| N0.5C0.5Sr3Cu2O7.4 | Tc=33 | [2] | ||||||||
| N0.5C0.5Sr2CaCu2O7.45 | Tc=91 | [2] | ||||||||
| N0.5C0.5Sr2.7Ca1.3Cu3O9.5 | Tc=91 | [2] | ||||||||
| N0.5C0.5Sr2.7Ca1.3Cu3O9.8 | Tc=101 | [2] | ||||||||
| N0.5C0.5Sr2.7Ca1.3Cu3O9.85 | Tc=101 | [2] | ||||||||
| N0.5C0.5Sr2Ca2Cu3O10.0 | [2] | |||||||||
| N0.5C0.5Sr2Ca3Cu4O10.0 | [2] | |||||||||
| N0.5C0.5Sr2Ca3Cu4O11.8 | Tc=99K | [2] | ||||||||
| N0.5C0.5Sr2Ca3Cu4O11.9 | Tc=101K | [2] | ||||||||
| N0.5C0.5Sr3.4Ca1.6Cu4O12.0 | Tc=105K | [2] | ||||||||
| YCaBa4Cu5(NO3)0.3(CO3)0.7O11 | superconductor Tc=82k | [15] | ||||||||
| hexakis(μ4-(R)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-diaqua-pentakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate tetrahydrate | monoclinic | P21 | a=15.6719 b=25.570 c=16.472 β=101.838° | colourless | [16] | |||||
| hexakis(μ4-(S)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-heptakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate pentahydrate | monoclinic | P21 | a=15.662 b=25.624 c=16.460 β=101.924° | [16] | ||||||
| pentakis(μ3-Glycine hydroxamato)-tetraaqua-(nitrato-O)-(nitrato-O,O')-penta-copper(ii)-europium(iii) tetrahydrate | [EuCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2O | triclinic | P1 | a=11.163 b=11.524 c=13.323 α=93.85° β=94.79° γ=107.14° Z=2 | 1624 | 2.425 | [17] | |||
| pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-gadolinium(iii) hydrate | [GdCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2O | triclinic | P1 | a=11.206 b=11.505 c=13.298 α=94.026° β=94.942° γ=107.558° Z=2 | 1620.2 | 2.440 | dark blue | [17] | ||
| pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-dysprosium(iii) hydrate | [DyCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.28H2O | triclinic | P1 | a=11.1083 b=11.4991 c=13.2894 α=93.923° β=94.771° γ=107.147° Z=2 | 1608.7 | 2.460 | dark blue | [17] | ||
| [HoCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.445H2O | triclinic | P1 | a=11.2027 b=11.4955 c=13.247 α=94.001° β=94.784° γ=107.518° Z=2 | 1613.0 | 2.467 | dark blue | [17] | |||
| bis(μ4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II)) tetranitrate trihydrate | ((Pt(NH3)2)4(CO3)2)(NO3)4·(H2O)3 | 2:4 | triclinic | P1 | a=11.324 b=12.151 c=10.926 α=103.792° β=111.266° γ=75.845° | blue | [18] | |||
| (Tl5/6Cr1/6)Sr4Cu2(CO3)1/2(NO3)1/2O7 | tetragonal | a = 3.8320 c = 16.4112 | [19] | |||||||
| [Pb6O4](OH)(NO3)(CO3) | 1:1 | orthorhombic | Pnma | a=30.557 b=5.809 c=7.183 Z=4 | 1274.9 | [20] |
References
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