The Europe/Africa Zone was one of three zones of regional competition in the 2013 Fed Cup.
Group I
- Venue: Municipal Tennis Club, Eilat, Israel (hard, outdoors)
- Date: 6–10 February
The sixteen teams were divided into four pools of four teams. The four pool winners will take part in play-offs to determine the two nations advancing to the World Group II Play-offs. The nations finishing last in their pools will take part in relegation play-offs, with the two losing nations being relegated to Group II for 2014.
Pools
| Pool A | CRO | BLR | AUT | GEO | |
| 1 |  Croatia (3–0) | 3–0 | 2–1 | 3–0 | |
|---|---|---|---|---|---|
| 2 |  Belarus (2–1) | 0–3 | 2–1 | 3–0 | |
| 3 |  Austria (1–2) | 1–2 | 1–2 | 3–0 | |
| 4 |  Georgia (0–3) | 0–3 | 0–3 | 0–3 |
| Pool B | GBR | HUN | POR | BIH | |
| 1 |  Great Britain (3–0) | 2–1 | 2–1 | 3–0 | |
|---|---|---|---|---|---|
| 2 |  Hungary (2–1) | 1–2 | 3–0 | 3–0 | |
| 3 |  Portugal (1–2) | 1–2 | 0–3 | 2–1 | |
| 4 |  Bosnia and Herzegovina (0–3) | 0–3 | 0–3 | 1–2 |
| Pool C | POL | ISR | ROU | TUR | |
| 1 |  Poland (3–0) | 2–1 | 2–1 | 3–0 | |
|---|---|---|---|---|---|
| 2 |  Israel (1–2) | 1–2 | 1–2 | 2–1 | |
| 3 |  Romania (1–2) | 1–2 | 2–1 | 1–2 | |
| 4 |  Turkey (1–2) | 0–3 | 1–2 | 2–1 |
| Pool D | BUL | NED | SLO | LUX | |
| 1 |  Bulgaria (3–0) | 3–0 | 3–0 | 3–0 | |
|---|---|---|---|---|---|
| 2 |  Netherlands (2–1) | 3–0 | 0–3 | 3–0 | |
| 3 |  Slovenia (1–2) | 0–3 | 0–3 | 2–1 | |
| 4 |  Luxembourg (0–3) | 1–2 | 0–3 | 0–3 |
Play-offs
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|
Poland and 
Great Britain advanced to World Group II play-offs.
Georgia and 
Bosnia and Herzegovina were relegated to Europe/Africa Group II in 2014.
Group II
- Venue: Bellevue Club, Ulcinj, Montenegro (outdoor clay)
- Dates: 17–20 April
The eight teams were divided into two pools of four teams. The two nations placing first and second will take part in play-offs to determine the two nations advancing to Group I. The nations finishing last in their pools will take part in relegation play-offs, with the two losing nations being relegated to Group III for 2014.
Pools
| Pool A | TUN | LAT | FIN | EST | |
| 1 |  Tunisia (3–0) | 2–1 | 2–1 | 2–1 | |
|---|---|---|---|---|---|
| 2 |  Latvia (2–1) | 1–2 | 3–0 | 3–0 | |
| 3 |  Finland (1–2) | 1–2 | 0–3 | 2–0 | |
| 4 |  Estonia (0–3) | 1–2 | 0–3 | 0–2 |
| Pool B | MNE | LTU | RSA | GRE | |
| 1 |  Montenegro (3–0) | 3–0 | 2–1 | 2–1 | |
|---|---|---|---|---|---|
| 2 |  Lithuania (2–1) | 0–3 | 2–1 | 2–1 | |
| 3 |  South Africa (1–2) | 1–2 | 1–2 | 2–1 | |
| 4 |  Greece (0–3) | 1–2 | 1–2 | 1–2 |
Play-offs
| Placing | A Team | Score | B Team |
|---|---|---|---|
| Promotion | Tunisia | 2–1 | Lithuania |
| Promotion | Latvia | 2–1 | Montenegro |
| Relegation | Finland | 2–1 | Greece |
| Relegation | Estonia | 1–2 | South Africa |
Group III
Venue: Terraten Club, Chișinău, Moldova (outdoor clay)
Dates: 8–11 May
The thirteen teams were divided into three pools of three teams and one pool of four. The four pool winners will take part in play-offs to determine the two nations advancing to Group II for 2014. The fourth nation in Pool D will not compete in the positional play-offs.
Pools
| Pool D | LIE | MAD | NOR | CYP | |
| 1 |  Liechtenstein (2–1) | 3–0 | 3–0 | 0–3 | |
|---|---|---|---|---|---|
| 2 |  Madagascar (2–1) | 0–3 | 2–1 | 2–1 | |
| 3 |  Norway (1–2) | 0–3 | 1–2 | 3–0 | |
| 4 |  Cyprus (1–2) | 3–0 | 1–2 | 0–3 |
Play-offs
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Egypt and 
Liechtenstein advanced to Europe/Africa Group II in 2014.